Enzymatic Production of Biodiesel

Enzymatic Production of Biodiesel?  The vast majority of biodiesel today is manufactured using chemical catalysts and methanol. A few problems are associated with this type of processing. These include 1) the need to remove free fatty acids (FFA) from the oil feedstock prior to reaction, 2) the need to remove phospholipids from the oil feedstock, and 3) the recovery of unreacted methanol and biodiesel purification and dewatering post-reaction. An up-and-coming technological solution to the chemical catalysis of oils and fats is to use enzymes, lipase, and phospholipase. Lipase enzymatically forms the methyl ester on FFA as well as doing transesterification on di- and triglycerides, yielding methanol and biodiesel. The phospholipase converts phospholipids to phosphates and FFA, increasing the substrates for the lipase. The yield of biodiesel without pretreating the raw oil can be much higher. Today the drawback of the enzymatic process is two-fold: the cost of the enzyme and the loss of enzyme in the methanol solution. New technologies are available to resolve both problems. The enzymes are being cost-effectively immobilized onto substrates that allow them to be recycled as well as protected from the methanol environment. In addition, the slow addition of methanol so that it is not in high concentration at any one moment is also effective. With these innovations and the possibility for much higher yields from lower-quality oils, it appears that enzymatic biodiesel may become the new industrial methodology.

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